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Redox Reaction

Redox reactions are reactions that involve either a transfer of electrons or a change in the oxidation numbers of the substances that are taking part in the reaction.

The substance gaining oxygen is oxidized, while the substance losing oxygen is reduced.

  • Losing electrons refers to oxidation. Gaining electrons refers to reduction.
    • Reducing agent: substance that loses electrons
    • Oxidizing agent: substance that accepts electrons

How to balance Redox Equations: (two methods)

  1. Using Oxidation-Number Changes

 

    Step 1: Assign the oxidation numbers to all of the atoms in an equation
    Step 2: Identify which atoms are oxidized and which atoms are reduced.
    Step 3: Use one bracketing line to connect the atoms that undergo
    oxidation and another bracketing line to connect those that undergo reduction.
    Step 4: Make the total increase in oxidation number equal to the total decrease in oxidation number by using the correct coefficients.
    Step 5: Balance the equation for both atoms and charge.

  1. Using Half Reactions

 

    Step 1: Write the unbalanced equation in ionic form
    Step 2: Separate oxidation and reduction processes in half-reactions
    Step 3: Balance the atoms in the half-reaction
    Step 4: Add enough electrons to one side of each half-reaction to balance the charges

            • The electrons will be added to opposite sides of the half-reaction

    Step 5: Multiply each half-reaction by an appropriate number that will make the number of electrons equal in both
    Step 6: Add the half-reactions to show an overall equation

    Step 7: Add the spectator ions and balance the equation

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